Why we prefer to choose lithium batteries
The answer is technical. But I have to make it accessible. This means the simplification of some technical concepts. So bear with me.
The Search For A High-Energy Battery
Imagine that you are a chemist hard at work at trying to find a new battery. Imagine it's circa 1960 and you are celebrating the anniversary of the lead-acid battery. You like the lead-acid battery, but are convinced that the world needs an extremely high-energy battery. We provide high quality cell phone batteries for many brands, such as nokia batteries, motorola batteries, samsung phone batteries. Brand new, never refurbished, 100% compatible, No memory effect. Over 500 full charge/discharge times.
You're not sure exactly why you need more energy , but you're obsessed with the Zeroth law of batteries which states that "The performance of any battery will fall (just) short of our expectations irrespective of the complexity of the device it is powering". Moreover your 5-year-old neighbor in Cupertino has convinced you that when he grows up he is going to make a computer that you can carry in your backpack, but that it will require a battery with a lot of energy. You know that if you want a lot of energy you need a high-voltage battery. Much higher than the 2 V of the lead-acid chemistry.
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So, you do what any decent chemist would do, and decide to drive across the bay to the library at the U. of California campus at Berkeley. You know that the library has a book that has extensive tables that tabulate the potential of various elements and you are sure you can find something that has a high voltage.
After some rummaging, you decide that the best battery in the world has to be one with a lithium anode and a fluorine cathode. The voltage is almost 6 V. You are excited, but also concerned that water breaks down at 1.2 V. You are also pretty sure that water and lithium should not be mixed. You still remember the mini fireworks that happened when you tried that experiment.
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You are also sure that you don't want to mess with fluorine. Your amputated finger on your right arm is evidence of your past attempts at working with fluorine and you have a new appreciation for the miracle of the opposable thumb. You decide to deal with the cathode problem later.
First things first. You need to get lithium to work.
You then find some interesting electrodeposition studies in a PhD thesis by Harris who was guided by Charles Tobias. The thesis has studies of the deposition of various alkali metals (sodium, lithium) in non-water-based solvents. One of these solvents, propylene carbonate, looks promising. You begin to think that maybe you have the ideal anode.






